Published March 1, 1957
| public
Journal Article
The Products from the Reaction of N-(2-Bromoallyl)-ethylamine with Sodium Amide
- Creators
- Bottini, Albert T.
- Roberts, John D.
Abstract
The principal product obtained from N-(2-bromoallyl)-ethylamine and sodium amide in liquid ammonnia has been shown to be N-ethylallenimine (I) as proposed by Ettlinger and Kennedy rather than N-ethylallylideneamine (II). N-Ethyl-propargylamine (III) was also isolated in small yield from this reaction. (2-chloroallyl)-ethylamine with potassium amide in liquid ammonia.
Additional Information
© 1957 American Chemical Society. Received September 4, 1956. Supported in part by a grant from the National Science Foundation. National Science Foundation Predoctoral Fellow, 1954-1957. We are indebted to Dr. Martin Ettlinger for drawing this problem to our attention in advance of publication6 and suggesting the use of n-m-r spectra in its solution.Additional details
- Eprint ID
- 61366
- Resolver ID
- CaltechAUTHORS:20151021-100828337
- NSF Predoctoral Fellowship
- Created
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2015-10-21Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 2130