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Published April 1, 1961 | public
Journal Article

Small-Ring Compounds. XXXIII. A Study by Nuclear Magnetic Resonance of the Extent of Isotope-position Rearrangement in the Vapor-phase Photochlorination of methyl-^(13)C-Cyclopropane

Abstract

Vapor-phase photochlorination of methyl-^(13)C-cyclopropane was found to yield cyclopropylcarbinyl-α-^(13)C chloride and allyl-γ-^(13)C-carbinyl chloride. Within the experimental error of the analytical method (nuclear magnetic resonance spectroscopy), no other ^(13)C-position isomers of the chlorides were formed.

Additional Information

© 1961 American Chemical Society. Received December 14, 1960. Supported in part by the Office of Naval Research, the Petroleum Research Fund of the American Chemical Society, and the National Science Foundation. Grateful acknowledgment is hereby made to the donors of the Petroleum Research Fund. National Science Foundation Faculty Fellow, 1959-1960.

Additional details

Created:
August 19, 2023
Modified:
October 25, 2023