Published February 1995
| public
Journal Article
Ion Distributions for Resonance-Enhanced Multiphoton Ionization of ClO
- Creators
- Wang, Kwanghsi
- McKoy, V.
Abstract
Results of theoretical studies of rotationally resolved photoelectron spectra for (2 + 1') resonance enhanced multiphoton ionization (REMPI) of the C ^2Σ^-, D ^2Σ^-, E ^2Σ^-, and F ^2Σ^- Rydberg states of ClO are presented. Cooper minima are predicted to occur in the electronic continua for photoionization of the D and F states and lead to unusual behavior in the ion rotational distributions. Strong partial wave I mixing is also predicted in the continua for the C and E states due to the nonspherical molecular ion potentials. These Cooper minima and l mixing make the associated photoionization dynamics quite nonatomiclike.
Additional Information
© 1995 American Chemical Society. Received: August 15, 1994. This work was supported by grants from the National Science Foundation, Air Force Office of Scientific Research, and the Office of Health and Environmental Research of the U.S. Department of Energy. We also acknowledge use of the resources of the Jet Propulsion Laboratory/California Institute of Technology CRAY Y-MP2E/232 Supercomputer.Additional details
- Eprint ID
- 61274
- Resolver ID
- CaltechAUTHORS:20151019-143015617
- NSF
- Air Force Office of Scientific Research (AFOSR)
- Department of Energy (DOE)
- Created
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2015-10-20Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 8971