Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published July 1, 1965 | public
Journal Article

Magnetic Resonance Spectroscopy. The Configurational Stability of Primary Grignard Reagents. 3,3-Dimethylbutylmagnesium Chloride

Abstract

Detailed examination of the temperature dependence of the n.m.r. spectra of 3,3-dimethylbutylmagnesium chloride and bis(3,3-dimethylbutyl)magnesium indicates that inversion of configuration at the -CH_2Mg center occurs rapidly in ether solution at room temperature.

Additional Information

© 1965 American Chemical Society. Received January 9, 1965. Supported in part by the Office of Naval Research and the National Science Foundation. Presented at the 10th Reaction Mechanisms Conference, Corvallis, Ore., June 24, 1964.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023