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Published March 1, 1968 | public
Journal Article

Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Coupling Constants in Organometallic Compounds

Abstract

High-resolution, natural-abundance ^(13)C nuclear magnetic resonance spectra have been obtained for the tetramethyl derivatives of group IV and the dimethyl derivatives of group IIb. The one-bond coupling constants between carbon and the spin 1/2 metal atoms as well as the "through-metal" vicinal carbon-proton coupling constants are discussed in terms of the Fermi contact coupling mechanism.

Additional Information

© 1968 American Chemical Society. Received October 4, 1967. Supported in part by the National Science Foundation and the Public Health Service Research Grant 11072-04 from the Division of General Medical Sciences. National Science Foundation Predoctoral Fellow, 1965-1967.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023