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Published June 1969 | public
Journal Article

Nuclear Magnetic Resonance Spectroscopy. Low-Temperature Studies of Diallylmagnesium

Abstract

Allylic organoalkali metal compounds have been observed to exhibit reversible changes in nmr spectra (e.g., AA'BB'C → AB_4 for allyllithium) over the temperature range from -100 to + 110º. In contrast, allymagnesium bromide is reported to display a simple AB_4 spectrum at -80º and diallylmagnesiurn to behave similarly from -60 to +37º in tetrahydrofuran.

Additional Information

© 1969 American Chemical Society. Received July 9, 1968. Supported in part by the National Science Foundation.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023