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Published October 1, 1969 | Published
Journal Article Open

Nuclear Magnetic Resonance Spectroscopy. Proton Spectra of Diallylmercury

Abstract

Changes have been observed in the nmr spectra of diallylmercury as a function of temperature which seem explicable in terms of allylic rearrangement and intermolecular exchange. Analysis of the proton spectra of diallylmercury spectra using a modified LAOCOON II computer program gave coupling constant and chemical shift parameters which reproduced the spectra at 60, 100, and 220 MHz.

Additional Information

© 1969 American Chemical Society. Received March 6, 1969. Supported in part by the National Science Foundation. We thank Professor S. I. Chan for assistance in securing 100-MHz spectra and for valuable suggestions. Mr. J. H. Prestegard obtained the 220-MHz spectrum and carried out the spin decoupling experiment.

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August 19, 2023
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October 24, 2023