Published July 1, 1972
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Hindered Rotation about the Carbon-Phosphorus Bond in tert-Butyldichlorophosphine
- Creators
- Roberts, J. B.
- Roberts, John D.
Abstract
The barrier to rotation about the C-P bond in tert-butyldichlorophosphine has been derived from a line-shape analysis of the proton nmr spectrum as a function of temperature. The ^3J_(PCCH) coupling constants are different for the two kinds of methyl protons, This difference suggests an influence of the bond orientation about the phosphorus-carbon bond on ^3J_(PCCH) for three-coordinate phosphorus compounds.
Additional Information
© 1972 American Chemical Society. Received September 24, 1971. Supported by the National Science Foundation.Additional details
- Eprint ID
- 60954
- Resolver ID
- CaltechAUTHORS:20151009-133525849
- NSF
- Created
-
2015-10-15Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and CrelIin Laboratories of Chemistry
- Other Numbering System Identifier
- 4335