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Published January 1974 | public
Journal Article

^1H, ^(13)C, and ^(15)N Nuclear Magnetic Resonance Studies of a Dinitrogen Complex of Permethyltitanocene. Evidence for Molecular Nitrogen Coordinated "Edge-on" to a Transition Metal

Abstract

In connection with the current interest in transition metal dinitrogen complexes and their possible roles in nitrogen-fixing reaction systems, we have obtained results which bear on the structure of a titanium dinitrogen complex in solution. We report here successful application of ^(15)N nmr spectroscopy to studies of a transition metal dinitrogen complex which provides a potentially powerful technique for elucidation of the structure of such complexes.

Additional Information

© 1974 American Chemical Society. Received January 23, 1974. This work has been supported by the Ford Motor Co., the Public Health Service through Research Grant No. GM-11072, Division of Medical Sciences, and by the National Science Foundation. We wish to thank Professors H. B. Gray and J. G. Gordon for helpful discussions.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023