Published January 1974
| public
Journal Article
^1H, ^(13)C, and ^(15)N Nuclear Magnetic Resonance Studies of a Dinitrogen Complex of Permethyltitanocene. Evidence for Molecular Nitrogen Coordinated "Edge-on" to a Transition Metal
Abstract
In connection with the current interest in transition metal dinitrogen complexes and their possible roles in nitrogen-fixing reaction systems, we have obtained results which bear on the structure of a titanium dinitrogen complex in solution. We report here successful application of ^(15)N nmr spectroscopy to studies of a transition metal dinitrogen complex which provides a potentially powerful technique for elucidation of the structure of such complexes.
Additional Information
© 1974 American Chemical Society. Received January 23, 1974. This work has been supported by the Ford Motor Co., the Public Health Service through Research Grant No. GM-11072, Division of Medical Sciences, and by the National Science Foundation. We wish to thank Professors H. B. Gray and J. G. Gordon for helpful discussions.Additional details
- Eprint ID
- 60934
- DOI
- 10.1021/ja00809a063
- Resolver ID
- CaltechAUTHORS:20151008-153202191
- Ford Motor Company
- GM-11072
- U.S. Public Health Service (USPHS)
- NSF
- Created
-
2015-10-10Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Noyes and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 4765