Published February 1, 1974
| public
Journal Article
Carbon-13 Magnetic Resonance Studies of Azoles. Tautomerism, Shift Reagent Effects, and Solvent Effects
- Creators
- Elguero, Jose
- Marzin, Claude
- Roberts, John D.
Abstract
The effects of substitution, lanthanide-shift reagents, solvent changes, and tautomerism were investigated on the ^(13)C chemical shifts of pyrrole, pyrazole, imidazole, s- and v-triazole, and tetrazole. It was concluded that ^(13)C chemical shifts are of limited value to ascertain the positions of tautomeric equilibrium for rapidly interconverting azole tautomers.
Additional Information
© 1974 American Chemical Society. Received August 24, 1973. This work is the 11th publication in the series "Nmr Studies of Heterocyclic Compounds." For previous papers in this series, see ref 50. The part of this research done at the California Institute of Technology was supported by the National Science Foundation. Université des Sciences et Techniques du Languedoc. California Institute of Technology.Additional details
- Eprint ID
- 60933
- DOI
- 10.1021/jo00917a017
- Resolver ID
- CaltechAUTHORS:20151008-153201930
- NSF
- Created
-
2015-10-10Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 4732