Published May 1, 1974
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Chemical Shifts of Chlorinated Organic Compounds
Abstract
The ^(13)C chemical shifts of a variety of perchlorocarbons, their hydrogen-substituted derivatives, and chlorocarbon ketones have been determined and assigned to specific carbons by high-resolution nuclear magnetic resonance spectroscopy. The assignment of ^(13)C resonances for these substances was often aided by ^(13)-^1H couplings and Overhauser enhancements observed in the carbon spectra of the hydrogen-substituted derivatives. Correlations between ^(13)C chemical shifts and structure were found for simple molecules and these correlations appear to provide the possibility of reasonable structural assignments for complex perchlorocarbons.
Additional Information
© 1974 American Chemical Society. Received March 6, 1973. Supported by the National Science Foundation, and by the Public Health Service, Research Grant No. GM-11072 from the Division of General Medical Services. Some of the data in this paper has been reported earlier by V. Mark and E. D. Well, J, Org. Chem.,36, 676 (1971). NATO Postdoctoral Fellow, 1970-1972.Additional details
- Eprint ID
- 60930
- DOI
- 10.1021/jo00923a026
- Resolver ID
- CaltechAUTHORS:20151008-153201063
- NSF
- GM-11072
- U.S. Public Health Service (USPHS)
- North Atlantic Treaty Organization (NATO)
- Created
-
2015-10-10Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 4654