Published October 1, 1974
| public
Journal Article
Nuclear Magnetic Resonance Spectroscopy. ^(13)C-^(15)N Coupling Constants as a Conformational Probe?
- Creators
- Berger, Stefan
- Roberts, John D.
Abstract
There have been several attempts to explain the variation in ^(13)C-^(l5)N coupling constants with the stereochemical orientation of the carbons with respect to the nitrogen lone pairs. Most of the substances investigated so far, however, have the possibility of averaging of coupling constants due to bond rotation and/or nitrogen inversion. The only relatively rigid substances looked at have had aromatic nitrogen, and, with these, other effects are expected to play a role.
Additional Information
© 1974 American Chemical Society. Received July 26, 1974. Supported by the National Science Foundation and by the Public Health Service, Research Grant No, GM-11072, from the Division of General Medical Sciences.Additional details
- Alternative title
- Nuclear magnetic resonance spectroscopy. Carbon-13-nitrogen-15 coupling constants as a conformational probe
- Eprint ID
- 60928
- DOI
- 10.1021/ja00828a036
- Resolver ID
- CaltechAUTHORS:20151008-153200440
- NSF
- GM-11072
- U.S. Public Health Service (USPHS)
- Deutsche Forschungsgemeinschaft (DFG)
- Created
-
2015-10-10Created from EPrint's datestamp field
- Updated
-
2023-10-24Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 4930