Published June 1, 1982
| public
Journal Article
Studies of the tautomerism of purine and the protonation of purine, and its 7- and 9-methyl derivatives, by nitrogen-15 nuclear magnetic resonance spectroscopy
- Creators
- Gonnella, Nina C.
- Roberts, John D.
Abstract
The nitrogen-15 NMR shifts of purine and its 7- and 9-methyl derivatives were measured at the natural-abundance level as a function of pH. The results made it possible for both the sites and magnitudes of protonation of purine and its derivatives to be determined. A semiquantitative determination was made of the position of the N7H-N9H tautomeric equilibria of purine in both water and dimethyl sulfoxide.
Additional Information
© 1982 American Chemical Society. Received May 22, 1981. Supported by the National Science Foundation and by the Public Health Service, Research Grant No. GM-11072 from the Division of General Medical Sciences.Additional details
- Eprint ID
- 60766
- DOI
- 10.1021/ja00375a038
- Resolver ID
- CaltechAUTHORS:20151005-120248928
- NSF
- GM-11072
- U.S. Public Health Service (USPHS)
- Created
-
2015-10-05Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 6440