Published January 1950
| public
Journal Article
Allylic Rearrangements. XXVIII. The Reaction of Butenylmagnesium Bromide with Hindered Ketones
Abstract
Recent studies of the addition reactions of the butenylmagnesium bromide have indicated that the butenyl Grignard reagent is probably best formulated as being exclusively crotylmagnesium bromide. The almost invariable formation of products containing α-methylallyl groups in carbonyl addition reactions has been suggested as due to the operation in the addition process of a six-membered cyclic mechanism.
Additional Information
© 1950 American Chemical Society. Received August 29, 1949. {John D. Roberts} Harvard University, National Research Fellow, 1945-1946.Additional details
- Eprint ID
- 60681
- DOI
- 10.1021/ja01157a061
- Resolver ID
- CaltechAUTHORS:20151001-104317256
- National Research Council
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2015-10-13Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field