Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published February 1946 | public
Journal Article

Allylic Rearrangements. XIX. Studies of the Ozonization of Allylic Systems

Abstract

During the investigation of the reactions of certain allylic systems under controlled conditions it has been necessary to devise methods for the analysis of mixtures of allylic isomers, the compositions of which could not be readily determined by the fractional distillation procedures used previously. Hurd has applied the ozonolysis method to the analysis of hexenyl bromides and the results are in satisfactory agreement with those obtained by the refractometric method. We have investigated the ozonization of other types of allylic systems giving particular attention to the influence of the group X on the products obtained from isomers of the type RCH=CH-CHR'X (I) and RCHX-CH=CHR' (II).

Additional Information

© 1946 American Chemical Society. Received September 27, 1945. Presented in part before the Division of Organic Chemistry at the Buffalo meeting of the American Chemical Society, September, 1942.

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023