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Published November 1991 | public
Journal Article

Peroxymonosulfate: An Alternative to Hydrogen Peroxide for the Control of Hydrogen Sulfide

Abstract

The oxidation of total dissolved sulfide, where S (-II)= H_2S + HS" + S_2^-, by peroxymonosulfate, HSO_5-, has been studied in wastewater. Peroxymonosulfate was found a more rapid and efficient oxidant of S (-II) than either H_2O_2 or Fe(II). The combination of per oxymonosulfate and hydrogen peroxide was additive in terms of S(-II) oxidation, while the combination of peroxymonosulfate and Fe(II) resulted in a decrease in the effectiveness of Fe(II) as an oxidant. Peroxy monosulfate has been shown to be a viable alternative to H_2O_2 for the control of sulfide-induced corrosion in concrete sewers.

Additional Information

© 1991 Water Environment Federation. Submitted for publication March 22, 1991; revised manuscript submitted June 11, 1991; accepted for publication June 17, 1991. Isabel Chen, Martha Shaw, and Joel Pedersen contributed to the experimental work. This work was funded by the County Sanitation Districts of Los Angeles County under CSD contract No 3082. Authors. A. Kotronarou is a Ph.D. candidate and M. R. Hoffmann is a professor in Environmental Engineering Science at the California Institute of Technology.

Additional details

Created:
August 20, 2023
Modified:
October 23, 2023