Published September 24, 1971
| public
Journal Article
Xenon as a Nucleophile in Gas-Phase Displacement Reactions: Formation of the Methyl Xenonium Ion
- Creators
- Holtz, David
-
Beauchamp, J. L.
Abstract
Xenon undergoes reaction with protonated methyl fluoride in the gas phase to form abundant quantities of the stable methyl xenonium ion, CH_3Xe^+. Estimated values for the xenon-carbon and krypton-carbon bond strengths in the rare gas-methyl molecular ions are 43 ± 8 and 21 ± 15 kilocalories per mole, respectively.
Additional Information
© 1971 American Association for the Advancement of Science. Received 7 June 1971. Work supported in part by the U.S. Atomic Energy Commission under grant AT(04-3)67-8. Contribution No. 4328 from the California Institute of Technology.Additional details
- Eprint ID
- 59047
- DOI
- 10.1126/science.173.4003.1237
- Resolver ID
- CaltechAUTHORS:20150729-081841016
- AT(04-3)67-8
- Atomic Energy Commission
- Created
-
2015-07-29Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Arthur Amos Noyes Laboratory of Chemical Physics
- Other Numbering System Identifier
- 4328