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Published 1992 | Published
Journal Article Open

Very low pressure pyrolysis of phenylacetic acid

Abstract

A Kinetic study of the very low pressure thermolysis of phenylacetic acid above 900 K reveals that its decomposition occurs in a concerted manner, yielding toluene and carbon dioxide, probably via a four-centre transition state [reaction (1)] [graphic omitted] with log[k_∞(1)/s^(–1)]=[(13 ± 0.3)–(12 200 ± 500)]/T.

Additional Information

© 1992 Royal Society of Chemistry. Paper 2/01513G; Received 23rd March, 1992.

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August 20, 2023
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