Published March 7, 2008
| Supplemental Material + Published
Journal Article
Open
Diazoalkanes react with a bis(phosphino)borate copper(I) source to generate [Ph_2BP^(tBu)_2]Cu(η^1-N_2CR_2), [Ph_2BP^(tBu)_2]Cu(CPh_2), and [Ph_2BP^(tBu)_2]Cu–N(CPh_2)(NCPh_2)
- Creators
- Mankad, Neal P.
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Peters, Jonas C.
Abstract
[Ph_2BP^(tBu)_2]Cu–L complexes react with diazoalkanes to generate structurally unusual η^1-diazoalkane adducts, a terminal carbene, and an η^1-azine adduct.
Additional Information
© 2008 Royal Society of Chemistry. Received 06 Sep 2007, Accepted 14 Dec 2007, First published online 17 Jan 2008. This work was funded by BP (MC2 program) and the NSF (CHE-0132216). N. P. M. is grateful for an NSF Graduate Research Fellowship. J. Christopher Thomas is acknowledged for preliminary reaction screening. John Keith gave useful advice regarding DFT calculations, and Larry Henling provided crystallographic assistance. DFT calculations were done at the Materials and Process Simulation Center at the California Institute of Technology.Attached Files
Published - b713687k.pdf
Supplemental Material - b713687k.txt
Supplemental Material - b713687k_si.pdf
Files
b713687k.pdf
Additional details
- Eprint ID
- 52513
- Resolver ID
- CaltechAUTHORS:20141209-143755965
- BP MC2 Program
- CHE-0132216
- NSF
- NSF Graduate Research Fellowship
- Created
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2014-12-09Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field