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Published August 28, 2011 | public
Journal Article

Homogeneous cobalt electrocatalysts for solar driven hydrogen evolution from water

Abstract

Towards the bigger picture of developing modular solns. for photoelectrochem. water splitting, catalytic proton redn. mediated by cobalt bis(iminopyridine) complexes has been explored in buffered aq. media over a broad range of pH conditions. The extremely rapid rates of electrocatalytic hydrogen evolution exhibited by firstgeneration catalysts will be discussed in conjunction with the performance of second-generation electrocatalysts. Details of electrochem. and photochem. mechanistic studies, kinetic competency, and the effects of reaction medium on H_2 evolution will also be presented.

Additional Information

© 2011 American Chemical Society.

Additional details

Created:
August 19, 2023
Modified:
October 26, 2023