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Published September 3, 2007 | Supplemental Material
Journal Article Open

Long-Lived and Efficient Emission from Mononuclear Amidophosphine Complexes of Copper

Abstract

A number of structurally unusual, monomeric amidophosphine complexes of copper exhibit luminescence properties that are unprecedented for monocopper systems in solution at room temperature. The complexes exhibit lifetimes as long as 150 μs in benzene and quantum efficiencies in the range of 0.16 < φ < 0.70.

Additional Information

© 2007 American Chemical Society Received May 16, 2007. Publication Date (Web): August 3, 2007. We acknowledge the NSF GOALI program. J.L.D. is grateful for an NSF GRF. Dr. Jay R. Winkler provided insightful insight. B.-L. Lin assisted with calculations. Luminescence measurements were carried out at the Beckman Institute Laser Resource Center.

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Supplemental Material - ic7009513-file003.cif

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August 19, 2023
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