Published May 30, 2003
| public
Journal Article
Zwitterionic Relatives to the Classic [(P–P)-Rh(solv)_2]^+ Ions: Neutral Catalysts Active for H—E Bond Additions to Olefins (E=C, Si, B)
- Creators
- Betley, Theodore A.
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Peters, Jonas C.
Abstract
Formally zwitterionic bis(phosphanyl)- and bis(amino)borate rhodium(I) complexes (see picture) can catalytically mediate the hydrogenation, hydroacylation, hydroboration, and hydrosilation of double bonds. These neutral systems are shown to be highly active, even under conditions incompatible with their isostructural, but formally cationic, relatives.
Additional Information
© 2003 Wiley-VCH Verlag GmbH & Co. Article first published online: 28 May 2003. Manuscript Revised: 10 Feb 2003. Manuscript Received: 16 Oct 2002. We thank the NSF (CHE-0132216), the ACS Petroleum Research Fund, and the Dreyfus Foundation for financial support. T.A.B. thanks the Department of Defense for a graduate research fellowship. Brian Stoltz and Jeremy May provided helpful discussions and a sample of 4-methyl-4-pentenal.Additional details
- Eprint ID
- 47552
- Resolver ID
- CaltechAUTHORS:20140729-100252822
- CHE-0132216
- NSF
- ACS Petroleum Research Fund
- Camille and Henry Dreyfus Foundation
- Department of Defense graduate research fellowship
- Created
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2014-07-29Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field