Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published March 28, 2004 | public
Journal Article

Synthesis and reactivity of nickel complexes supported by the tris(phosphino) borate ligand [PhB(Ch_2PPh_2)_3]^-

Abstract

The chemistry of nickel complexes supported by phosphine donor ligands has gained recent interest due to the ability of these species to catalyze a variety of chemical transformations. A series of divalent, monovalent, and zerovalent nickel complexes supported by the strongly electron-releasing, monoanionic tris(phosphino) borate ligand, [PhBP_3]=[PhB(CH_2PPh 2)_3]^-, have been synthesized to explore their coordination chemistry and reactivity. The characterization of these complexes will be presented, with comparisons drawn to isostructural nickel complexes supported by neutral phosphine ligands.

Additional Information

© 2004 American Chemical Society.

Additional details

Created:
August 19, 2023
Modified:
October 26, 2023