Published September 17, 2003
| Supplemental Material
Journal Article
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Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d^7 Ion
- Creators
- Jenkins, David M.
-
Peters, Jonas C.
Abstract
This Communication describes a pseudotetrahedral d^(7) complex, [PhBP_(3)]Co(OSiPh_(3)), that exhibits thermally induced spin-crossover both in solution and in the solid state. Magnetic crossover behavior is achieved by confluence of the X-type ligand and the tripodal auxiliary employed. Four-coordinate platforms of the present geometry type may offer a new approach to magnetic spin-crossover behavior distinct from their electronically related pseudooctahedral counterparts.
Additional Information
© 2003 American Chemical Society. Received May 16, 2003. Publication Date (Web): August 22, 2003. We thank the NSF (CHE-0132216) and the DOE (PECASE) for financial support. D.M.J. acknowledges an NSF graduate research fellowship. We are grateful to the Beckman Institute (Caltech) for use of the SQUID magnetometer, and to Mike Day and Larry Henling for crystallographic assistance.Attached Files
Supplemental Material - ja036198fsi20030711_043608.pdf
Supplemental Material - ja036198fsi20030711_043637.cif
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ja036198fsi20030711_043608.pdf
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Additional details
- Alternative title
- Solution and Solid-State Spin-Crossover Behavior in a Pseudotetrahedral d7 Ion
- Eprint ID
- 47430
- DOI
- 10.1021/ja036198f
- Resolver ID
- CaltechAUTHORS:20140723-132440365
- CHE-0132216
- NSF
- Department of Energy (DOE) PECASE award
- NSF Graduate Research Fellowship
- Created
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2014-07-24Created from EPrint's datestamp field
- Updated
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2021-11-10Created from EPrint's last_modified field