Published February 1, 1948
| Published
Journal Article
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The Molecular Structure of Dimethyltrisulfide, (CH_3)_2S_3
- Creators
- Donohue, Jerry
- Schomaker, Verner
Abstract
Dimethyltrisulfide (CH_3)_2S_3 has been investigated by the electron diffraction method. The molecule was found to have the chain configuration, with the following interatomic distances and angles: C-H=1.09A (assumed), C-S=1.78±0.04A, S-S=2.04A, ±0.02A, ∠H-C-S=112° (assumed), ∠S-S-S=104°±5°, and ∠C-S-S=104°±5°. The results also suggest that the C-S bonds oscillate with rather large amplitude about a mean position approximately 106° out of the plane of the three sulfur atoms.
Additional Information
© 1948 American Institute of Physics. Received July 1, 1947. The work herein was done under Contract OEMsr-753 between the National Defense Research Committee and the California Institute of Technology. Contribution No. 1108 from the Gates and Crellin Laboratories of Chemistry, California Institute of Technology.Attached Files
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Additional details
- Eprint ID
- 45516
- Resolver ID
- CaltechAUTHORS:20140506-091635695
- OEMsr-753
- National Defense Research Committee
- Caltech
- Created
-
2014-05-06Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field
- Other Numbering System Name
- Caltech Gates and Crellin Laboratories of Chemistry
- Other Numbering System Identifier
- 1108