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Published September 9, 2004 | Supplemental Material
Journal Article Open

A high-performance cathode for the next generation of solid-oxide fuel cells

Abstract

Fuel cells directly and efficiently convert chemical energy to electrical energy. Of the various fuel cell types, solid-oxide fuel cells (SOFCs) combine the benefits of environmentally benign power generation with fuel flexibility. However, the necessity for high operating temperatures (800–1,000 °C) has resulted in high costs and materials compatibility challenges. As a consequence, significant effort has been devoted to the development of intermediate-temperature (500–700 °C) SOFCs. A key obstacle to reduced-temperature operation of SOFCs is the poor activity of traditional cathode materials for electrochemical reduction of oxygen in this temperature regime2. Here we present Ba_(0.5_Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3-delta) (BSCF) as a new cathode material for reduced-temperature SOFC operation. BSCF, incorporated into a thin-film doped ceria fuel cell, exhibits high power densities (1,010 mW cm^(-2) and 402 mW cm^(-2) at 600 °C and 500 °C, respectively) when operated with humidified hydrogen as the fuel and air as the cathode gas. We further demonstrate that BSCF is ideally suited to 'single-chamber' fuel-cell operation, where anode and cathode reactions take place within the same physical chamber. The high power output of BSCF cathodes results from the high rate of oxygen diffusion through the material. By enabling operation at reduced temperatures, BSCF cathodes may result in widespread practical implementation of SOFCs.

Additional Information

© 2004 Nature Publishing Group. Received 25 February 2004; Accepted 25 June 2004. This work was funded by the Defense Advanced Research Projects Agency, Microsystems Technology Office. Additional support was provided by the National Science Foundation through the Caltech Center for the Science and Engineering of Materials. Selected oxygen permeability measurements were carried out in the Laboratory of Reaction Engineering and Energy, Institute of Research on Catalysis, CNRS, France, during the visit of Z.P.S. there, hosted by C. Mirodatos.

Attached Files

Supplemental Material - nature02863-s1.pdf

Supplemental Material - nature02863-s10.pdf

Supplemental Material - nature02863-s12.pdf

Supplemental Material - nature02863-s2.pdf

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Supplemental Material - nature02863-s5.pdf

Supplemental Material - nature02863-s6.pdf

Supplemental Material - nature02863-s7.pdf

Supplemental Material - nature02863-s8.pdf

Supplemental Material - nature02863-s9.pdf

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