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Published January 2, 2004 | Supplemental Material
Journal Article Open

High performance solid acid fuel cells through humidity stabilization

Abstract

Although they hold the promise of clean energy, state-of-the-art fuel cells based on polymer electrolyte membrane fuel cells are inoperable above 100°C, require cumbersome humidification systems, and suffer from fuel permeation. These difficulties all arise from the hydrated nature of the electrolyte. In contrast, "solid acids" exhibit anhydrous proton transport and high-temperature stability. We demonstrate continuous, stable power generation for both H_2/O_2 and direct methanol fuel cells operated at ∼250°C using a humidity-stabilized solid acid CsH_2PO_4 electrolyte.

Additional Information

© 2003 American Association for the Advancement of Science. Received for publication 28 August 2003. Accepted for publication 12 November 2003. Published Online November 20 2003. Supported by the NSF, Division of Materials Research, and the Office of Naval Research, Office of Electrochemical Power, Science, and Technology.

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