Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published October 18, 2013 | Supplemental Material
Journal Article Open

Aldehyde-Selective Wacker-Type Oxidation of Unbiased Alkenes Enabled by a Nitrite Co-Catalyst

Abstract

Breaking the rules: Reversal of the high Markovnikov selectivity of Wacker-type oxidations was accomplished using a nitrite co-catalyst. Unbiased aliphatic alkenes can be oxidized with high yield and aldehyde selectivity, and several functional groups are tolerated. ^(18)O-labeling experiments indicate that the aldehydic O atom is derived from the nitrite salt.

Additional Information

© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Issue published online: 14 Oct 2013; Article first published online: 13 Sep 2013; Manuscript Received: 2 Aug 2013. We thank Scott Virgil for technical assistance. We acknowledge KAUST, KFUPM, and NSF for funding and the SNSF for a fellowship to B.M.

Attached Files

Supplemental Material - anie_201306756_sm_miscellaneous_information.pdf

Files

anie_201306756_sm_miscellaneous_information.pdf
Files (766.0 kB)
Name Size Download all
md5:5b3bb1a4bcc1509875d79c25aa7f36be
766.0 kB Preview Download

Additional details

Created:
August 22, 2023
Modified:
October 25, 2023