Published June 19, 2013
| Accepted Version + Supplemental Material
Journal Article
Open
Synthesis of Highly Cis, Syndiotactic Polymers via Ring-Opening Metathesis Polymerization Using Ruthenium Metathesis Catalysts
Abstract
The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.
Additional Information
© 2013 American Chemical Society. Received: June 4, 2013; Published: June 19, 2013.Attached Files
Accepted Version - nihms497126.pdf
Supplemental Material - Supporting_info.pdf
Files
Supporting_info.pdf
Files
(3.5 MB)
| Name | Size | Download all |
|---|---|---|
|
md5:bbe682fee3f24165611e9456fb266ffa
|
1.0 MB | Preview Download |
|
md5:69e9f0716b110e965ed1a7d0577dcb10
|
2.5 MB | Preview Download |
Additional details
- PMCID
- PMC3773019
- Eprint ID
- 41430
- Resolver ID
- CaltechAUTHORS:20130919-155320130
- R01-GM031332
- NIH
- CHE-1212767
- NSF
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- RR027690
- NIH
- Created
-
2013-09-30Created from EPrint's datestamp field
- Updated
-
2021-11-10Created from EPrint's last_modified field