An Approach to 8-Membered, 16-Membered and 24-Membered Sulfur- Containing Heterocycles Via Homolytic Cycloaddition of Alkynes with Butane-1,4-Dithiol

Creators: Troyansky, Emmanuil I.; Ismagilov, Rustem F.; Korneeva, Ekaterina N.; Pogosyan, Mariam S.; Nikishin, Gennady I.

Abstract

Homolytic cycloaddition of butane-1,4-dithiol with alkynes offers a facile one-pot route to 8-membered 1,4-dithiocanes and 16-and 24-membered crown thioethers, 1,4,9,12-tetrathiacyclohexadecanes and 1,4,9,12,17,20-hexathiacyclotetracosanes.

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Copyright © 1995 jointly by The Russian Academy of Sciences and The Royal Society of Chemistry (Turpion Ltd). Received 15 November 1994. Available online 11 March 2008. The authors are indebted for financial support to the Russian Foundation for Fundamental Research (project no. 93-03-18110) and the International Science Foundation (grant no. MPL000).

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Resource type: Journal Article
Publisher: Elsevier
Published in: Mendeleev Communications, 5(1), 18-20, ISSN: 0959-9436.

Created:: August 22, 2023
Modified:: October 24, 2023