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Published May 27, 2013 | public
Journal Article

Group 4 Transition-Metal Complexes of an Aniline–Carbene–Phenol Ligand

Abstract

Attempts to install a tridentate aniline–NHC–phenol (NCO) ligand on titanium and zirconium led instead to complexes resulting from unexpected rearrangement pathways that illustrate common behavior in carbene–early-transition-metal chemistry.

Additional Information

© 2013 American Chemical Society. Received: February 27, 2013; Published: May 9, 2013. This work was supported by a KAUST Center-In-Development Grant to King Fahd University of Petroleum and Minerals (Dhahran, Saudi Arabia) and the USDOE Office of Basic Energy Sciences (Grant No. DE-FG03-85ER13431). The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU award to the California Institute of Technology (CHE-0639094).

Additional details

Created:
August 19, 2023
Modified:
October 24, 2023