Melting of compressed iron by monitoring atomic dynamics

Abstract

We present a novel method for detecting the solid–liquid phase boundary of compressed iron at high temperatures using synchrotron Mössbauer spectroscopy (SMS). Our approach is unique because the dynamics of the iron atoms are monitored. This process is described by the Lamb–Mössbauer factor, which is related to the mean-square displacement of the iron atoms. Focused synchrotron radiation with 1 meV bandwidth passes through a laser-heated ^(57)Fe sample inside a diamond-anvil cell, and the characteristic SMS time signature vanishes when melting occurs. At our highest compression measurement and considering thermal pressure, we find the melting point of iron to be T_M=3025±115 K at P=82±5 GPa. When compared with previously reported melting points for iron using static compression methods with different criteria for melting, our melting trend defines a steeper positive slope as a function of pressure. The obtained melting temperatures represent a significant step toward a reliable melting curve of iron at Earth's core conditions. For other terrestrial planets possessing cores with liquid portions rich in metallic iron, such as Mercury and Mars, the higher melting temperatures for compressed iron may imply warmer internal temperatures.

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