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Published October 15, 1965 | Erratum + Published
Journal Article Open

Dissociation and Isomerization of Vibrationally Excited Species. III

Abstract

The equations of Part I for the specific and over‐all unimolecular reaction‐rate constants are extended slightly by including centrifugal effects in a more detailed way and by making explicit allowance for possible reaction‐path degeneracy (optically or geometrically isomeric paths). The expression for reaction‐path degeneracy can be applied to other types of reactions in discussions of statistical factors in reaction rates.

Additional Information

© 1965 American Institute of Physics. Received 20 May 1965. Supported in part by a grant from the National Science Foundation. Presented in part at a symposium on reaction kinetics, American Physical Society, St. Louis, Missouri, March 1963 Supported in part by a grant from the National Science Foundation. Presented in part at a symposium on reaction kinetics, American Physical Society, St. Louis, Missouri, March 1963.

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Erratum - MARjcp65ecorr.pdf

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Created:
August 19, 2023
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October 18, 2023