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Published 1973 | Published
Journal Article Open

Effect of 2-Substitution on the Rearrangement of 1-Cyclopropylvinyl Cations

Abstract

2-Substitution in 1-cyclopropylvinyl cations produces a steric effect on cation generation and solvent trapping, but an electronic charge-stabilizing effect on cyclopropyl-to-cyclobutyl rearrangement.

Additional Information

© 1973 Royal Society of Chemistry. Received 25th Afiril 1973; Corn. 572. We thank the National Institutes of Health, the Alfred P. Sloan Foundation, and the Camille and Henry Dreyfus Foundation for financial support.

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August 19, 2023
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