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Published July 1979 | public
Journal Article

The generation of C-glycosides through the enolate Claisen rearrangement

Abstract

The [3,3]-sigmatropic rearrangements of silyl ketene acetals obtained from aliphatic esters of furanoid and pyranoid glycals is described. The heterocyclic γ,δ-unsaturated carboxylic acids II are produced in good yields. A new preparation of furanoid and pyranoid glycals is described.

Additional Information

© 1979 National Research Council of Canada. Received January 25. 1979. Dedicated to the memory of R. H. F. Manske. This work was made possible by a grant from the National Institutes of Health, Grant No. HL 21367-01.

Additional details

Created:
August 19, 2023
Modified:
October 18, 2023