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Published June 1, 1989 | Published
Journal Article Open

A new mechanism for exchange processes observed in the compounds [M(η-C_5H_5)_2(exo-η-RCH = CH_2)H], M = Nb and Ta

Abstract

Dynamic n.m.r. studies of the exchange processes in the complexes [M(η-C_5H_5)(exo-η-RCH=CH_2)H], M = Nb, Ta, lead to the proposal of a new mechanism involving intermediates with agostic bonding.

Additional Information

© 1989 Royal Society of Chemistry. Received, 20th December 1988; Com. 8/04965C. We thank NATO (research grant 287-84) for support, and the Gas Research Institute for partial support, of this work. We thank D. O'Hare, C. M. Dobson, and S. J. Heyes for helpful discussion.

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August 19, 2023
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