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Published February 25, 2011 | Accepted Version
Journal Article Open

Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

Abstract

Adaptable metallaboratranes: A tris- (phosphino)borane ligand stabilizes both low-valent Fe-N_2 complexes and a mid-valent imido species with a Fe≡NAr bond, thanks to its ability to shuttle between trigonal-bipyramidal and pseudotetrahedral geometries by elongation of the apical iron–boron bond (see picture)

Additional Information

© 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. Received: November 4, 2010. Article first published online: 26 January 2011. This work was supported by the NIH (GM 070757). M.-E.M. acknowledges a Fellowship for Prospective Researchers from the Swiss National Science Foundation. We thank Charlene Tsay and Larry Henling for crystallographic assistance, as well as David VanderVelde for assistance with DOSY experiments and Angelo Di Bilio for EPR measurements.

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August 22, 2023
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