Published September 13, 2010
| Supplemental Material + Accepted Version
Journal Article
Open
Synthesis and Structures of Fused N-Heterocylic Carbenes and Their Rhodium Complexes
- Creators
- Li, Jean
- Stewart, Ian C.
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Grubbs, Robert H.
Abstract
New procedures for the synthesis of N-heterocyclic carbenes with multiple fused rings have been developed utilizing a key ring-closing metathesis step. Rhodium complexes were obtained via the pentafluorophenyl carbene adducts. Solid-state structural behaviors of the new carbene ligands were analyzed via X-ray crystallography.
Additional Information
© 2010 American Chemical Society. Received April 2, 2010. Publication Date (Web): August 5, 2010. The authors wish to thank the NIH (F32GM078734 and K99GM084302 to I.C.S. and 5RO1GM31332 to R.H.G.) for generous financial support. J.L. thanks the National Science Foundation for a Graduate Research Fellowship. This research was made with government support under and awarded by DoD, Air Force Office of Scientific Research, National Defense Science and Engineering Graduate (NDSEG) Fellowship, 32 CFR 168a. Dr.Michael W. Day and Lawrence M. Henling are thanked for crystallographic work, and Dr. David Vandervelde is thanked for NMR spectroscopy work.Attached Files
Accepted Version - nihms227186.pdf
Supplemental Material - om100262x_si_001.pdf
Supplemental Material - om100262x_si_002.cif
Files
om100262x_si_001.pdf
Additional details
- PMCID
- PMC2992343
- Eprint ID
- 20053
- DOI
- 10.1021/om100262x
- Resolver ID
- CaltechAUTHORS:20100920-145414074
- F32GM078734
- NIH Postdoctoral Fellowship
- K99GM084302
- NIH
- 5RO1GM31332
- NIH
- NSF Graduate Research Fellowship
- 32 CFR 168a
- National Defense Science and Engineering Graduate (NDSEG) Fellowship
- Created
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2010-09-24Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field