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Published September 21, 2010 | Supplemental Material + Published
Journal Article Open

Ligand design for site-selective installation of Pd and Pt centers to generate homo- and heteropolymetallic motifs

Abstract

The modular synthesis of a series of nitrogen-rich polydentate ligands that feature a common pincer-type framework is reported. These ligands allow for site-selective installation of palladium and platinum to give rise to bi- and trimetallic complexes that have d^(8)–d^(8) interactions.

Additional Information

© 2010 Royal Society of Chemistry. Received 15th February 2010, Accepted 18th June 2010. This work was funded in part by the NSF (CHE-0750234). DLMS is grateful for funding from the NSF-GRFP and the MIT Presidential Fellowship Program. Dr Peter Mu¨ ller is acknowledged for insightful discussions.

Attached Files

Published - Suess2010p11137Chem_Commun__Camb_.pdf

Supplemental Material - C003163A.TXT

Supplemental Material - C003163A.pdf

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