Published July 28, 2010
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Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation
Abstract
Cationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H_2 in less than 60 s at 25 °C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.
Additional Information
© 2010 American Chemical Society. Received February 27, 2010. Publication Date (Web): July 2, 2010. This research was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science, and Technology (2010-0018456). This research was performed in collaboration with the Hydrogen Energy R&D Center, which is funded by the 21st Century Frontier R&D Program of MEST.Attached Files
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Additional details
- Eprint ID
- 19490
- DOI
- 10.1021/ja101685u
- Resolver ID
- CaltechAUTHORS:20100818-095527649
- 2010-0018456
- Ministry of Education, Science, and Technology (Korea)
- Created
-
2010-08-18Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field