Published May 12, 2010
| Supplemental Material
Journal Article
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Synthesis and C−C Coupling Reactivity of a Dinuclear Ni^I−Ni^I Complex Supported by a Terphenyl Diphosphine
Abstract
Mono- and bimetallic complexes of nickel supported by a terphenyl diphosphine have been synthesized. The reported complexes show diverse metal−arene interactions in the solid state. Reactions of an o,o′-biphenyldiyl dinickel complex with CO and dichloroalkanes lead to fluorene derivatives, indicating the formation of carbon−carbon bonds at a bimetallic moiety.
Additional Information
© 2010 American Chemical Society. Received March 4, 2010. We thank Lawrence M. Henling for crystallographic assistance. We are grateful to Caltech, bp, NSF GRFP (S.L.), and the Caltech SURF Program (A.V.) for funding. The Bruker KAPPA APEXII X-ray diffractometer was purchased via an NSF CRIF:MU Award to Caltech (CHE-0639094).Attached Files
Supplemental Material - ja101699a_si_001.pdf
Supplemental Material - ja101699a_si_002.cif
Supplemental Material - ja101699a_si_003.cif
Supplemental Material - ja101699a_si_004.cif
Supplemental Material - ja101699a_si_005.cif
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Additional details
- Eprint ID
- 18504
- DOI
- 10.1021/ja101699a
- Resolver ID
- CaltechAUTHORS:20100601-111503988
- Caltech
- British Petroleum
- NSF Graduate Research Fellowship
- Caltech Summer Undergraduate Research Fellowship (SURF)
- Created
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2010-06-02Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field