Published April 2010
| Supplemental Material
Journal Article
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Tris(hydroxypropyl)phosphine Oxide: A Chiral Three-Dimensional Material with Nonlinear Optical Properties
Abstract
The achiral C_(3v) organic phosphine tris(hydroxypropyl)phosphine oxide (1) crystallizes in the unusual chiral hexagonal space group P6_3. The structure is highly ordered because each phosphine oxide moiety forms three hydrogen bonds with adjacent hydroxy groups from three different molecules. The properties of the crystals and the presence of hydrogen bonding interactions were investigated using single crystal Raman spectroscopy. The crystals show nonlinear optical properties and are capable of efficient second harmonic generation.
Additional Information
© 2010 American Chemical Society. Received January 27, 2010. Publication Date (Web): March 17, 2010. We thank Larry Henling for assistance with face indexing the crystal and George Rossman for assistance with single crystal Raman spectroscopy. This research was supported in part by the Starter Grant Award from the Spectroscopy Society of Pittsburgh (to E. C.Y.Y.) and the NSF Center for Chemical Innovation (CCI Powering the Plant, Grants CHE-0802907 and CHE-0947829 to H.B.G.).Attached Files
Supplemental Material - cg1001286_si_001.pdf
Supplemental Material - cg1001286_si_002.cif
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Additional details
- Eprint ID
- 18317
- DOI
- 10.1021/cg1001286
- Resolver ID
- CaltechAUTHORS:20100517-091141484
- Spectroscopy Society of Pittsburgh
- CHE-0802907
- NSF
- CHE-0947829
- NSF
- Created
-
2010-06-07Created from EPrint's datestamp field
- Updated
-
2021-11-08Created from EPrint's last_modified field
- Caltech groups
- CCI Solar Fuels