Published September 14, 2009
| Supplemental Material
Journal Article
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Selective Oxidation of sp^3 C-H Bonds in Water Catalyzed by a Glycinate-Platinum(II) Complex
Abstract
In aqueous solution, [Pt^(II)(glycinato)Cl_2]^− catalyzes oxidation by [Pt^(IV)Cl_6]^(2−) of the methyl group of p-toluenesulfonate to the corresponding alcohol and aldehyde, with no further oxidation to the carboxylic acid. Both rate and selectivity are improved in comparison to the original Shilov system that employs [Pt^(II)Cl_n(H_2O)_(4−n)]^(2−n) as the catalyst.
Additional Information
Copyright © 2009 American Chemical Society. Received April 8, 2009. Publication Date (Web): August 3, 2009. This work has been generously supported by BP through the MC2 program. An NSF Graduate Research Fellowship to G.S.C. is gratefully acknowledged. We thank Bo-Lin Lin for helpful discussions in the preparation of this paper. Supporting Information: Text giving detailed experimental data. This material is available free of charge via the Internet at http://pubs.acs.org.Attached Files
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Additional details
- Eprint ID
- 15794
- DOI
- 10.1021/om900267w
- Resolver ID
- CaltechAUTHORS:20090911-153559302
- BP MC2 program
- NSF Graduate Research Fellowship
- Created
-
2009-10-07Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field