Published April 23, 2009
| Supplemental Material + Published
Journal Article
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Experimental realization of catalytic CH_4 hydroxylation predicted for an iridium NNC pincer complex, demonstrating thermal, protic, and oxidant stability
Abstract
A discrete, air, protic, and thermally stable (NNC)Ir(III) pincer complex was synthesized that catalytically activates the CH bond of methane in trifluoroacetic acid; functionalization using NaIO_4 and KIO_3 gives the oxy-ester.
Additional Information
© Royal Society of Chemistry 2009. Received (in Cambridge, UK) 5th January 2009, Accepted 12th March 2009. First published on the web 23rd April 2009. We thank Chevron Energy Technology Company and Scripps Florida for financial support. Electronic supplementary information (ESI) available: Experimental details and DFT xyz coordinates. CCDC 697907–697909. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/b823303aAttached Files
Published - Young2009p4446Chem_Commun.pdf
Supplemental Material - Youngb823303a.pdf
Supplemental Material - Youngb823303a.txt
Files
Youngb823303a.pdf
Additional details
- Eprint ID
- 15617
- Resolver ID
- CaltechAUTHORS:20090904-113907339
- Chevron Energy Technology Co.
- Scripps Florida
- Created
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2009-09-22Created from EPrint's datestamp field
- Updated
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2021-11-08Created from EPrint's last_modified field