Welcome to the new version of CaltechAUTHORS. Login is currently restricted to library staff. If you notice any issues, please email coda@library.caltech.edu
Published 2009 | Published + Supplemental Material
Journal Article Open

C-H activation in strongly acidic media. The co-catalytic effect of the reaction medium

Abstract

Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt^(II)(bpym)Cl_2 (bpym = 2,2'-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.

Additional Information

© 2009 The Royal Society of Chemistry. Received (in Cambridge, UK) 5th December 2008, Accepted 2nd February 2009 First published as an Advance Article on the web 12th March 2009.

Attached Files

Published - Ahlquist2009p1702Chem_Commun__Camb_.pdf

Supplemental Material - Ahlquist2009p1702Chem_Commun__Camb__supp.pdf

Files

Ahlquist2009p1702Chem_Commun__Camb__supp.pdf
Files (656.2 kB)
Name Size Download all
md5:0c470abe407c805adc7415640b9c3295
120.9 kB Preview Download
md5:e2922056acebc80acd5e361abf5a77e0
535.3 kB Preview Download

Additional details

Created:
August 20, 2023
Modified:
October 18, 2023